October 2009. Opening of our 21 warehousing facilities alongside Supermarket RDC’s in UK and Ireland.
International Freight Forwarders
Telephone0151 284 8867
Fax0151 203 3140
www.supplychainsolution.co.uk
Customer ID:
Password:About our customer login option
 
Home>Road Freight>Hazardous Goods
HAZARDOUS GOODS BY ROAD

We are able to carry all classifications of hazardous cargo by Road, Airfreight or Seafreight. Our European Partner specialises in movements of this nature, and our customers include members of the Oil and Gas Industry, Military Organisations and Environmental Agencies.

Detailed below is technical information concerning the classifications involved in the transportation of hazardous cargo. You will also find a large section on the carriage of Radioactive Material which we hope proves of some help.

Movement of Hazardous Cargo

Class 1 - Explosive Dangerous Goods: Explosive substances and articles used to produce explosions or pyrotechnic effect

Class 1.1 - Explosives with a mass explosion hazard

Class 1.2 - Explosives with a severe projection hazard

Class 1.3 - Explosives with a fire, blast or projection hazard but not a mass explosion hazard

 

Class 1.4 - Explosives with a minor fire or projection hazard

Class 1.5 - An insensitive substance with a mass explosion hazard

Class 1.6 - Extremely insensitive articles

 
 

Class 2.1 - Flammable gas

Class 2.2 - Non-flammable, compressed gas

Class 2.3 - Toxic gas

 
     

Class 3 - Flammable liquids

     
 

Class 4.1 - Flammable solids

Class 4.2 - Spontaneously combustible solids

Class 4.3 - Combustible solids when in contact with water

 
   

Class 5.1 - Oxidizer

Class 5.2 - Organic peroxide

   
   

Class 6.1 - Toxic substances

Class 6.2 - Infectious substances

   
 

Class 7 - Radioactive components

Class 8 - Corrosive materials

Class 9 - Miscelaneous dangerous compounds

 
 

Transport of Radioactive Materials

  • About twenty million packages of all sizes containing radioactive materials are routinely transported worldwide annually on public roads, railways and ships.
  • These use robust and secure containers. At sea, they are generally carried in purpose-built ships.
  • Since 1971 there have been more than 20 000 shipments of used fuel and high-level wastes (over 80 000 tonnes) over many million kilometres.
  • There has never been any accident in which a container with highly radioactive material has been breached, or has leaked.

About 20 million transports of radioactive material (which may be either a single package or a number of packages sent from one location to another at the same time) take place around the world each year. Radioactive material is not unique to the nuclear fuel cycle and most transports of such material are not fuel cycle related. Radioactive materials are used extensively in medicine, agriculture, research, manufacturing, non-destructive testing and minerals' exploration.

The regulatory control of shipments of radioactive material is independent of its intended application and the same safety procedures are employed, whatever the intended end-use.

Nuclear fuel cycle facilities are located in various parts of the world and materials of many kinds need to be transported between them. Many of these are similar to materials used in other industrial activities. However, the nuclear industry's fuel and waste materials are radioactive, and it is these 'nuclear materials' about which there is most public concern.

Nuclear materials have been transported since before the advent of nuclear power over fifty years ago. The procedures employed are designed to ensure the protection of the public and the environment. For the generation of a given quantity of electricity, the amount of nuclear fuel required is very much smaller than the amount of any other fuels. Therefore, the conventional risks and environmental impacts associated with fuel transport are greatly reduced with nuclear power.

Materials being transported

Transport is an integral part of the nuclear fuel cycle. There are some 430 nuclear power reactors in operation in 32 countries but uranium mining is viable in only a few areas. Furthermore, in the course of over forty years of operation by the nuclear industry, a number of specialised facilities have been developed in various locations around the world to provide fuel cycle services. It is clear that there is a need to transport nuclear fuel cycle materials to and from these facilities. Indeed, most of the material used in nuclear fuel is transported several times during its its progress through the fuel cycle. Transports are frequently international, and are often over large distances. Nuclear materials are generally transported by specialised transport companies.

The term 'transport' is used in this document only to refer to the movement of material between facilities, i.e. through areas outside such facilities. Most transports of nuclear fuel material occur between different stages of the cycle, but occasionally a material may be transported between similar facilities. When the stages are directly linked (such as mining and milling), it is sometimes advantageous to construct facilities for the different stages on the same site and no transport is then required.

With very few exceptions, nuclear fuel cycle materials are transported in solid form. The following table shows the principal nuclear material transport activities:

From:To:Material:Notes:
MiningMillingOreRare: usually on the same site
MillingConversionUranium oxide concentrate ("Yellowcake") 
ConversionEnrichmentUranium hexafluoride (UF6) 
EnrichmentFuel FabricationEnriched UF6 
Fuel FabricationPower GenerationFresh (unused) fuel 
Power GenerationUsed Fuel StorageUsed fuelAfter on-site storage
Used Fuel StorageDisposalUsed fuel 
Used Fuel StorageReprocessingUsed fuel 
ReprocessingConversionUranium oxideCalled reprocessed uranium
ReprocessingFuel FabricationPlutonium oxide 
ReprocessingDisposalFission ProductsVitrified (incorporated into glass)
All FacilitiesStorage/DisposalWaste materialsRare: usually on the same site

Although some waste disposal facilities are located adjacent to the facilities that they serve, utilising one disposal site to manage the wastes from several facilities usually reduces environmental impacts. When this is the case, transport of the wastes from the facilities to the disposal site will be required.

Packaging

The principal assurance of safety in the transport of nuclear materials is the design of the packaging, which must allow for foreseeable accidents. The consignor bears primary responsibility for this. Many different nuclear materials are transported and the degree of potential hazard from these materials varies considerably. Different packaging standards have been developed to recognise that increased potential hazard calls for increased protection.

'Type A' packages are designed to withstand minor accidents and are used for medium-activity materials such as medical or industrial radioisotopes. Ordinary industrial containers are used for low-activity material such as U3O8.

Packages for high-level waste (HLW) and used fuel are robust and very secure containers are known as 'Type B' packages. They also maintain shielding from gamma and neutron radiation, even under extreme conditions. There are over 150 kinds of Type B packages, and the larger ones cost some US$1.6 million each.

In France alone, there are some 750 shipments each year of Type B packages, among 15 million shipments classified as 'dangerous materials', 300,000 of these being radioactive materials of some kind.

Smaller amounts of high-activity materials (including plutonium) transported by aircraft will be in 'Type C' packages, which give greater protection in all respects than Type B packages in accident scenarios.

Radiation protection

Since nuclear materials are radioactive, it is important to ensure that radiation exposure of both those involved in the transport of such materials and the general public along transport routes is limited. Packaging for nuclear materials includes, where appropriate, shielding to reduce potential radiation exposures. In the case of some materials, such as fresh uranium fuel assemblies, the radiation levels are negligible and no shielding is required. Other materials, such as used fuel and high-level waste, are highly radioactive and purpose-designed containers with integral shielding are used. To limit the risk in handling of highly radioactive materials, dual-purpose containers (casks), which are appropriate for both storage and transport of used nuclear fuel, are often used.

As with other hazardous materials being transported, packages of nuclear materials are labelled in accordance with the requirements of national and international regulations. These labels not only indicate that the material is radioactive, by including a radiation symbol, but also give an indication of the radiation field in the vicinity of the package.

Personnel directly involved in the transport of nuclear materials are trained to take appropriate precautions and to respond in case of an emergency.

Regulation of transport

Since 1961 the International Atomic Energy Agency (IAEA) has published advisory regulations for the safe transport of radioactive material. These regulations have come to be recognised throughout the world as the uniform basis for both national and international transport safety requirements in this area. Requirements based on the IAEA regulations have been adopted in about 60 countries, as well as by the International Civil Aviation Organisation (ICAO), the International Maritime Organisation (IMO), and regional transport organisations.

The IAEA has regularly issued revisions to the transport regulations in order to keep them up to date. The main publication on which other IAEA transport regulations are based is Safety Series No. ST-l, Regulations for the Safe Transport of Radioactive Material.

The objective of the regulations is to protect people and the environment from the effects of radiation during the transport of radioactive material.

Protection is achieved by:

  • Containment of radioactive contents
  • Control of external radiation levels
  • Prevention of criticality
  • Prevention of damage caused by heat

The fundamental principle applied to the transport of radioactive material is that the protection comes from the design of the package, regardless of how the material is transported.

Transport of uranium oxide from mines and uranium hexafluoride

Uranium oxide concentrate, sometimes called yellowcake, is transported from the mines to conversion plants in 200-litre drums packed into normal shipping containers. No radiation protection is required beyond having the steel drums clean and within the steel container. From the conversion plant, the uranium is in the form of uranium hexafluoride, which again is barely radioactive but has significant chemical toxicity. It is in special containers, which also function for storage.

Transport of uranium fuel assemblies

Uranium fuel assemblies are manufactured at fuel fabrication plants. The fuel assemblies are made up of ceramic pellets formed from pressed uranium oxide that has been sintered at a high temperature (over 1400°C). The pellets are aligned within long, hollow, metal rods, which in turn are arranged in the fuel assemblies, ready for introduction into the reactor. Different types of reactors require different types of fuel assembly, so when the fuel assemblies are transported from the fuel fabrication facility (where they are manufactured) to the nuclear power reactor, the contents of the shipment will vary with the type of reactor receiving it.

In Western Europe, Asia and the US, the most common means of transporting uranium fuel assemblies is by truck. A typical truckload supplying a light water reactor contains 6 tonnes of fuel. In the countries of the former Soviet Union, rail transport is most often used. Intercontinental transports are mostly by sea, though occasionally transport is by air.

The annual operation of a 1000 MWe light water reactor requires an average fuel load of 27 tonnes of uranium dioxide, containing 24 tonnes of enriched uranium. The assemblies containing this are normally supplied in one consignment occupying 4 to 5 trucks.

The fuel assemblies are transported in packages specially constructed to protect the precision-made fuel assemblies from damage during transport. Uranium fuel assemblies have a low radioactivity level and radiation shielding is not necessary.

Fuel assemblies contain fissile material and in some circumstances fissile material can spontaneously become critical, i.e. start a self- sustaining, nuclear chain reaction, releasing energy. Criticality is prevented by the design of the package, the arrangement of the fuel assemblies within the package, limitations on the amount of material contained within the package, and on the number of packages carried in one shipment.

Transport of LLW and ILW

Low-level and intermediate-level wastes (LLW and ILW) are generated throughout the nuclear fuel cycle. The transport of these wastes is commonplace and they are safely transported to waste treatment facilities and storage sites.

Low-level radioactive wastes are a variety of materials that emit low levels of radiation, slightly above normal background levels. They often consist of solid materials, such as clothing, tools, or contaminated soil. Low-level waste is transported from its origin to waste treatment sites, or to an intermediate or final storage facility.

A variety of radionuclides give low-level waste its radioactive character. However, the radiation levels from these materials are very low and the packaging used for the transport of low-level waste does not require special shielding.

Low-level wastes are moved by road, rail, and internationally, by sea. However, most low-level waste is only transported within the country where it is produced.

Low-level wastes are transported in drums, often after being compacted in order to reduce the total volume of waste. The drums commonly used contain up to 200 litres of material. Typically, 36 standard, 200 litre drums go into a 6-metre transport container.

The composition of intermediate-level wastes is broad, but they require shielding. Much ILW comes from nuclear power plants and reprocessing facilities.

Intermediate-level wastes are taken from their source to an interim storage site, a final storage site (as in Sweden), or a waste treatment facility. They are transported by road, rail and sea.

The radioactivity level of intermediate-level waste is higher than low-level waste. The classification of radioactive wastes is decided for disposal purposes, not on transport grounds. The transport aspects of intermediate-level waste take into account any specific properties of the material, and provide shielding.

Classification of radioactive wastes

There are several systems of nomenclature in use, but the following is generally accepted:

  • Exempt waste - excluded from regulatory control because radiological hazards are negligible.
  • Low-level waste (LLW) - contains enough radioactive material to require action for the protection of people, but not so much that it requires shielding in handling or storage.
  • Intermediate-level waste (ILW) - requires shielding. If it has more than 4000 Bq/g of long-lived (over 30 year half-life) alpha emitters it is categorised as "long-lived" and requires more sophisticated handling and disposal.
  • High-level waste (HLW) - sufficiently radioactive to require both shielding and cooling, generates >2 kW/m 3 of heat and has a high level of long-lived alpha-emitting isotopes.

Transport of used fuel

When used fuel is unloaded from a nuclear power reactor, it contains: 96% uranium, 1% plutonium and 3% of fission products (from the nuclear reaction) and transuranics).

Used fuel looks the same as fresh fuel but when the fuel assembly is removed from a reactor it will be emitting high levels of both radiation and heat. It is stored in water pools adjacent to the reactor to allow the initial heat and radiation levels to decrease. Typically, used fuel is stored for at least five months before it can be transported, although it may be stored there long-term.

From the reactor site, used fuel is transported by road, rail or sea to either an interim storage site or a reprocessing plant where it will be reprocessed.

Used fuel assemblies are shipped in Type B casks. These casks are shielded with steel, or a combination of steel and lead, and can weigh up to 110 tonnes each when empty. A typical transport cask holds up to 6 tonnes of used fuel.

Since 1971 there have been some 7000 shipments of used fuel (over 80 000 tonnes) over many million kilometres with no property damage or personal injury, no breach of containment, and very low dose rate to the personnel involved (e.g. 0.33 mSv/yr per operator at La Hague). This includes 40,000 tonnes of used fuel shipped to Areva's La Hague reprocessing plant, at least 30,000 tonnes of mostly UK used fuel shipped to UK's Sellafield reprocessing plant, 7140 t used fuel in 160 shipments from Japan to Europe by sea (see below) and 4500 tonnes of used fuel shipped around the Swedish coast.

In the USA alone, one percent of the 300 million packages of hazardous material shipped each year contain radioactive materials. Of this, about 250,000 contain radioactive wastes from US nuclear power plants, and 25 to 100 packages contain used fuel. Most of these are in robust 125-tonne Type B casks carried by rail, each containing 20 tonnes of used fuel.

Transport of plutonium

Plutonium is separated during the reprocessing of used fuel. It is normally then made into mixed oxide (MOX) fuel.

Plutonium is transported, following reprocessing, as an oxide as this is its most stable form. Plutonium oxide is a solid, and normally transported as a powder in sealed packages. It is insoluble in water and only harmful to humans if it enters the lungs.

Plutonium oxide is transported in several different types of packages and each can contain several kilograms of material. Criticality is prevented by the design of the package, limitations on the amount of material contained within the package, and on the number of packages carried on a transport vessel.

Plutonium is subjected to physical protection controls and special physical protection measures apply to plutonium transports.

A typical transport consists of one truck carrying one protected shipping container. The container holds a number of packages with a total weight varying from 80 to 200 kg of plutonium oxide.

A sea shipment may consist of several containers, each of them holding between 80 to 200 kg of plutonium in sealed packages.

Transport of vitrified waste

The highly radioactive wastes (especially fission products) created in the nuclear reactor are segregated and recovered during the reprocessing operation. These wastes are incorporated in a glass matrix by a process known as 'vitrification', which stabilises the radioactive material.

The molten glass is then poured into a stainless steel canister where it cools and solidifies. A lid is welded into place to seal the canister. The canisters are then placed inside a Type B cask, similar to those used for the transport of used fuel.

The quantity per shipment depends upon the capacity of the transport cask. Typically a vitrified waste transport cask contains up to 28 canisters of glass. The main characteristics of the canister are as follows:

  • height (with lid) = 1.34 m
  • outside diameter = 0.43 m
  • weight (empty) = 90 kg

So far, France is the only country that has carried out transports of vitrified waste. Since 1995, there have been five transports (two to Germany by rail, six to Japan by sea). This figure should increase in the years to come.

In the UK, storage is on the same site as reprocessing and vitrification.

Sea shipments of wastes

Some 300 sea voyages have been made carrying used nuclear fuel or separated high-level waste over a distance of more than 8 million kilometres. The major company involved has transported over 4000 casks, each of about 100 tonnes, carrying 8000 tonnes of used fuel or separated high-level wastes. A quarter of these have been through the Panama Canal.

In Sweden alone, more than 80 large transport casks are shipped annually from nuclear power stations (all on the coast) to a central interim waste storage facility called CLAB. Each 80 tonne cask has steel walls 30 cm thick and holds 17 BWR or 7 PWR fuel assemblies. The used fuel is shipped to CLAB after it has been stored for about a year at the reactor, during which time heat and radioactivity diminish considerably. A purpose-built 2000 tonne ship is used for moving the used fuel. Some 4500 tonnes of used fuel had been shipped around the coast to CLAB by the end of 2007.

Shipments of used fuel from Japan to Europe for reprocessing use 94-tonne Type B casks, each holding a number of fuel assemblies (e.g. 12 PWR assemblies, total 6 tonnes, with each cask 6.1 metres long, 2.5 metres diameter, and with 25 cm thick forged steel walls). More than 160 of these shipments took place from1969 to the 1990s, involving more than 4000 casks, and moving several thousand tonnes of highly radioactive used fuel - 4200t to UK and 2940t to France.

Return shipments from Europe to Japan since 1995 are of vitrified high-level wastes in stainless steel canisters. Up to 28 canisters (total 14 tonnes) are packed in each 98-tonne steel transport cask. Each is 6.6 metres long and 2.4 metres diameter, with a 25 cm thick wall. Over 1995-2007 twelve shipments were made from France of vitrified HLW comprising 1310 canisters containing almost 700 tonnes of glass. In 2008 return shipments from the UK are due to commence, and there will be about 11 shipments to 2016.

Apart from Sweden's dedicated small ship, there are five purpose-built 5100 tonne ships, with elaborate safety provisions, which carry the casks. These have double hulls with impact-resistant structures between the hulls, together with duplication and separation of all essential systems to provide high reliability and also survivability in the event of an accident. Twin engines operate independently. Each ship can carry up to 17 used fuel flasks or 14 waste transport flasks.

The ships are owned by Pacific Nuclear Transport Ltd. They conform to all relevant international safety standards, notably one known as INF-3 (Irradiated Nuclear Fuel class 3) set by the International Maritime Organisation. This allows them to carry highly radioactive materials such as high- level wastes, used nuclear fuel, mixed-oxide (MOX) fuel, and plutonium. PNTL is now owned by International Nuclear Services Ltd (INS, 62.5%), Japanese utilities (25%) and Areva (12.5%). PNTL is currently renewing its fleet. INS is 51% owned by Sellafield Ltd and 49% by the UK's Nuclear Decommissioning Authority and is managed by Sellafield Ltd.

Within Europe, used fuel in casks has often been carried on normal ferries, e.g. across the English Channel.

Accident scenarios

There has never been any accident in which a Type B transport cask containing radioactive materials has been breached or has leaked.

For the radioactive material in a large Type B package in sea transit to become exposed, the ship's hold (inside double hulls) would need to rupture, the 25 cm thick steel cask would need to rupture, and the stainless steel flask or the fuel rods would need to be broken open. Either borosilicate glass (for reprocessed wastes) or ceramic fuel material would then be exposed, but in either case these materials are very insoluble.

The transport ships are designed to withstand a side-on collision with a large oil tanker. If the ship did sink, the casks will remain sound for many years and would be relatively easy to recover since instrumentation including location beacons would activate and monitor the casks.

 

For all enquiries please complete our "online quotation" form or email sales@supplychainsolution.co.uk

Member of The Liverpool Chamber of Commerce ISO Certified Member of The Road Haulage Association Member of The Chartered Institute of Logistics Member of The Turkish-British Chamber of Commerce  
  Terms and Conditions Website Disclaimer
  Transport Directory - Directory of UK transport companies and providers.